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To help capture a serial rapist-turned-killer, FBI Special Agent Don Eppes recruits his genius brother Charlie, who uses a mathematical equation to identify the killer's point of origin by working back from the crime scene locations.
Charlie accurately predicts where a band of bank robbers will strike next. But when Don and his team confront them, a massive shoot-out occurs leaving four people, including an officer, dead. The outcome disturbs Charlie and he retreats into the family garage to work out an unsolvable math problem that he also plunged into after his mother became ill a year earlier. But Don needs his brother's help and tries to get Charlie to return to the case.
Various people in the L.A. area with seemingly nothing in common start to become extremely sick and die on the same day. Don fears bioterrorists may have released a deadly virus into the enviroment. While he tries to discover whether anyone is behind the outbreak, Charlie tries to locate the point of origin.
After an engineering student at CalSci is found dead from an apparent suicide, Charlie convinces Don to launch an investigation after he reads the student's thesis that asserted that the architecturally magnificent Cole Center in Los Angeles is structurally unstable. Although reluctant at first, Don and his FBI agents discover that the student's findings were correct and uncover a dangerous and surprising conspiracy. Meanwhile, Alan prepares for a first date and convinces Don and Terry to join them, hoping they might rekindle their old romance.
When a 5-year-old girl is kidnapped from her birthday party, Don and Terry lead the investigation but must rely on Charlie's help, as the girl's father, Ethan, is also a mathematician. Charlie realizes the kidnapper's motive when Ethan reveals that he is close to solving Riemann's Hypothesis, a difficult math problem. If solved, the solution could not only earn him with $1 million but could break the code for Internet security, unlocking the world's biggest financial secret.
While consulting with the National Transportation Safety Board at the scene of the wreck, Don learns that this tragedy is one of a series of recreated accidents involving railroad negligence. As is the pattern with the previous train wrecks, an undecipherable numerical code is left at the site, which Don recruits Charlie to solve. By breaking the code, Charlie is able to establish that this accident was a recreation of a deadly wreck that left only one survivor several years ago. Don's investigation leads him and his team to a dangerous standoff with their suspect, who has surprising ties to the railway system.
Don learns that counterfeiters are at work producing small-denomination bills, and that they have taken an artist hostage to draw the images for the fake money. If the missing woman isn't located soon, Don fears that she will be killed when her work is finished on the phony cash. The counterfeiters have already murdered at least five people, two of whom stole money from them. The case is made more difficult for Don when his former lover, now a Secret Service agent, is assigned to it.
A man wanted for stock fraud is found garroted in his apartment, and the crime is eerily similar to a murder committed a year earlier, a case in which Don closed when an ex-con confessed. Now, Don must re-investigate the old case to determine if he put an innocent man in jail. He asks Charlie to go over the evidence to see if he missed anything the first time around.
The city is in a panic as a sniper goes on a shooting spree and randomly kills several people, including a postal worker. The investigation reveals that more than one shooter is at work. As Charlie works the case, he's frustrated by a sniper expert Don brings in to help out.
A truck carrying radioactive material is stolen, and the thieves threaten to set off a dirty bomb in L.A. in 12 hours if they aren't paid $20 million. While Don attempts to track down the truck, Charlie tries to come up with the most likely location where the bomb may be detonated to inflict the most damage to the population.
A senior computer-science researcher working on a classified government project is found murdered in his Hollywood Hills home, and data stolen from his computer. The investigation reveals that the victim was going through a bitter divorce, and was trying to keep his wife from getting his money. Charlie also learns that the project the man was working on may involve baseball.
Don and Agent Quimby of the NTSB investigate eyewitness accounts of a mysterious unidentified object flying dangerously close to downtown Los Angeles that has raised concern of a terrorist attack. After Charlie is recruited to help with the investigation, it is discovered that the flying object is part of a new technology that could revolutionize air travel. But the investigation takes a turn when they learn that the lead engineer is found murdered.
Don calls on his FBI fugitive recovery skills to track down two violent felons who escape after a prison bus crash.
Don and Charlie investigate the murder of a judge's wife who was shot in her garage. It's unclear whether she was the intended target or her husband, who was hearing a death penalty case involving a gang leader. As the investigation continues, Don reconnects with a prosecutor whose life may also be in danger.
Don and his team are called in when a woman attempting to rob a jewelry store in Beverly Hills is shot by a security guard. Charlie assists the FBI by using the keyless remote from the woman's car to help identify her and locate the store owner's kidnapped wife and daughter.
The FBI becomes involved in the stalking of a popular singer after she is threatened by an intruder in her house and reveals a series of threatening letters she's received through the mail. Charlie determines the letters are from two different people after analyzing the handwriting. When a photographer is found dead near the singer's house, Don believes the photographer was murdered and his death is somehow related to the stalking case.
Don and Megan are called to the murder scene when the CFO of a powerful energy company - who was about to testify against her fellow executives - is murdered at her home and her son is the only witness. Knowing there could be thousands of disgruntled ex-employees, Don asks Charlie to narrow the list.
Don uncovers a secret code that begins the hunt for a skilled and trained assassin, and the efforts by the FBI to save the life of a Colombian exile living in Los Angeles.
Don and his team are summoned to locate the person who released potentially lethal gas in the city's subway system.
When a father is killed in a home invasion, Don and his team investigate the connection between the murder and a rash of robberies in the upscale community.
Megan feels responsible for an agent's death following an explosion at a meth house the FBI had targeted for a bust. When the kingpin eludes capture, it's discovered he may also be involved in child pornography.
After four people nearly die from poisoning, Don learns someone is tampering with nonprescription drugs. When the perpetrator publishes a manifesto in a local paper, Don is led to believe the person may be a former employee of the drug company that manufactured the drug.
When a researcher who specializes in Native American antiquities is killed at the museum where she works, the FBI is called in because the museum is on federal land.
An arsonist sets a fire at a car dealership that kills a sales person. The name of an extremist environmental group is spray-painted on the scene, but the group denies involvement. It becomes Don's task to determine whether the group or someone else is responsible. Charlie is called in to help figure out if there is a pattern to the fires that would help provide a profile of the arsonist.
When Don and his team are called to the scene of the murder of a Los Angeles gang member, they learn they are investigating the murder of another agent who had been working undercover.
A murder investigation at a Los Angeles card club leads the FBI to a complicated card-counting scheme involving college students.
When an Asian teenager is found in the basement of an old downtown hotel where she was apparently being tortured, the investigation soon reveals the girl and three other missing women, are victims of a black market organ-harvesting scheme. Amita assists the FBI by communicating with the girl, who is from the same part of India where Amita's family once lived.
When a DNA synthesizer with the capability of customizing diseases is stolen from the campus where Charlie teaches, Don fears the thieves may be terrorists out to start or advance a bio-warfare program and also believes the theft was an inside job.
A retired agent is brought in to help with the investigation surrounding a bomb that explodes outside an Army recruiting center that appears to be similar to one that occurred 35 years ago at an ROTC office. Don must determine whether the original bomber has returned or if a copycat is responsible.
Charlie becomes outraged when he learns a psychic led the police to the crime scene where the bodies of illegal immigrants were found on government-owned land, and he sets out to prove the man is a fraud.
While talking on her cellphone, a woman named Saida is taken and killed the day before she had an important interview. Saida was an Iraqi citizen in the states to make a documentary. She was an activist who received death threats. Don and his team work with Agent Kareem Allawi. Charlie has dinner with Susan Berry an old friend who is in town for a book signing. Both of them seem to have a liking for one another.
Don and his team investigate a school shooting only to be surprised with one of the suspects. As Don and his team investigate the motive behind two students' deadly school shooting, Charlie uses the school's radio frequency identification system to track the shooters' movements through the school's hallways. But when Charlie notices an abnormal pattern, Don and his agents reevaluate the evidence and discover an unlikely third participant.
Don takes a deeper look at his life after he investigates the circumstances surrounding an ex-girlfriend's death. When an ATF agent is found dead amid questionable circumstances, Don demands to take on the case, which revolves around an elaborate bank heist, after he learns the victim is his ex-girlfriend. As the pressure of his job mounts, Don recognizes the impact his professional life has on his personal life and he decides to investigate his flirtation with AUSA Robin Brooks.
After an unknown man opens fire in the FBI offices, Don and his team must investigate his motive and his connection to a dangerous arms dealer who is on trial. After almost getting shot, Charlie is visibly shaken and reluctant to return to the offices, hindering his contribution in the case.
Don and his family are in danger when they become the targets of the suspects Don and the team are investigating. An FBI investigation into a computer hacking scam, which taps into a bank's system to gain access to customer's identities and financial assets, becomes personal for Don when the Russian mob spearheading it comes after him and threatens the safety of Charlie and Alan.
Don enlists Charlie's help when the bodies of five young Asian girls found washed up are suspected of being infected with the Avian influenza virus. To prevent the potential spread of the Avian flu, Don puts a rush on the investigation, which takes a surprising turn when David and Colby discover a clue on one of the girls' bodies. Meanwhile, Amita considers a move to Harvard University, which causes Charlie to re-evaluate his feelings for her.
The FBI investigates a rapist-turned-serial killer. Meanwhile, Charlie struggles with unresolved memories of his deceased mother.
While Don and his team are faced with trying to capture a 30-year-old teacher (Dickens) and her 17-year-old boyfriend/student (Gallagher) who are on a violent cross-country crime spree, one of their own gets caught in the crossfire. Meanwhile, after Charlie and Amita share an intimate moment, he freaks out when he thinks Amita has accepted a teaching position at CalSci to be with him. Later, Alan decides he is ready to find a place of his own.
Desperate to rescue their fellow agent, Don and his team close in on finding Megan, who is being held hostage by a disturbed teacher (Kim Dickens) on a vicious crime spree. The FBI faces a stand off with Crystal who refuses to let Megan go unless the FBI releases her boyfriend (David Gallagher) in exchange. During the wait, however, Megan manages to get Crystal to open up about her motive, which triggers a violent reaction and puts Megan in even more danger.
Don and the rest of the team find themselves in the midst of a confusing case. The investigation into a missing painting turns grim as a murder plot surfaces. Add Nazis to the mix, and things take an even more interesting turn!
Don and the team attempt to figure out what happened when a Chinese interpreter turns up dead.
Don and the rest of the team investigate several attacks occurring on LA highways that may be connected.