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Chuck Bartowski is an average computer geek until files upon files of government secrets are downloaded into his brain. He is soon scouted by the CIA and NSA to act in place of their computer.
As Chuck is beginning to adapt to his new life as a spy, a doctor who could possibly "cure" Chuck is murdered. Chuck then begins a high-speed fight for his life, all while trying decide which of his two colleagues might be out to get him. Meanwhile, Chuck's sister, Ellie, invites Sarah to dinner to "meet the family".
Chuck needs the help of Morgan and the Nerd Herd to prove that he is ready to become the store's assistant manager; Sarah and John assign Chuck his first undercover spy mission to foil a terrorism plot.
Chuck's latest mission has him raiding a Malibu mansion to grab a million dollar diamond being used to fund terrorism. Tagging along is an attractive but less-than-trustworthy DEA agent.
After his intuition is wrong while working on a stakeout, Chuck feels morally obligated to make things right, even when both Sarah and Casey refuse to help with Chuck's new mission. Meanwhile, Morgan has to participate in a sales competition that could decide his fate at Buy More.
In this Halloween episode of Chuck, Chuck meets a Federal agent just like him: a computer whiz whose brain is important national security. However, Chuck soon has a personal dilemma arise when he has to decide whether or not to turn the man into Sarah and Casey or help him escape his handlers.
Returning to Stanford, the University that expelled him, Chuck has to help a former professor who is a Government agent being hunted for a sensitive top-secret file he has in his possession. At the same time, Chuck learns much about himself and about the death of his friend Bryce Larkin.
Chuck must learn to balance a real love life with his cover love life when he meets a charming young woman by the name of Lou. At the same time, his relationship with Sarah gets interesting when the duo must explain their sexual relations with Ellie and Captain Awesome on a double date. Meanwhile, there is trouble when someone is using "truth" poison in order to retrieve codes for nuclear facilities.
Not all of Sarah's feelings for Chuck may have been a cover, she finds out, as Chuck begins dating Lou, a sandwich maker. When things couldn't get even more complicated, Lou turns out to be a part of a smuggling ring.